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| 顶空气相色谱法测定醇醚产品中微量环氧乙烷 | |
| 引用本文： | 宋唯,沈绪东,柴再胜.顶空气相色谱法测定醇醚产品中微量环氧乙烷[J].化工科技,2011,19(1):32-34. |
| 作者姓名： | 宋唯 沈绪东 柴再胜 |
| 作者单位： | 1. 中国石油吉林石化公司电石厂,吉林吉林,132022 2. 中国石油东北炼化工程有限公司,吉林设计院,吉林吉林132002 3. 中国石油吉林石化公司研究院,吉林吉林,132021 |
| 摘 要： | 建立了测定醇醚产品中微量环氧乙烷的顶空气相色谱法.样品经80℃、30min静态顶空后,采用气相色谱-氢火焰离子化检测器进行检测,外标法定量.该方法加标回收率在88.3％~104.7％,相对标准偏差在0.66％~3.94％.应用此法杂质干扰少,对醇醚产品中微量环氧乙烷在0.4~25mg／kg线性关系良好(7>0.998)... |
| 关 键 词： | 顶空气相色谱法 测定 微量 环氧乙烷 |
Determination of micro ethylene oxide in glycol ether by headspace GC method |
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| SONG Wei,SHEN Xu-dong,CAI Zai-sheng.Determination of micro ethylene oxide in glycol ether by headspace GC method[J].Science & Technology In Chemical Industry,2011,19(1):32-34. | |
| Authors: | SONG Wei SHEN Xu-dong CAI Zai-sheng |
| Affiliation: | SONG Wei ,SHEN Xu-dong ,CAI Zai-sheng (1.Calcium Carbide Factory of Jilin Petrochemical Company,Ltd.,PetroChina,Jilin 132022,China;2.Jilin Besign Institute of CNPC Northeast Refining and Chemical Engineering Co.Ltd.,PetroChina,Jilin 132002,China;3.Research Institute of Jilin Petrochemical Co.Ltd.,PetroChina,Jilin 132021,China) |
| Abstract: | In this paper,the determination method of micro ethylene oxide in the product of glyco ether by headspace gas chromatography was established.With hydrogen flame ionization detector,the detecting test was carried out.The addition standard recovery is 88.3%~104.7%.The relative standard deviation is 0.66%~3.94%.This method has many advantages as follows：simple operation,high accuracy,good repeatability,and so on.It＇s application has achieved good effect. |
| Keywords: | Headspace GC Determination Micro Ethyene oxide |
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