| Meso-四(对十六烷氧基萘基)卟啉的合成及光谱性能 |
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| 引用本文： | 陶敏莉,刘东志,周雪琴.Meso-四(对十六烷氧基萘基)卟啉的合成及光谱性能[J].化学工业与工程,2004,21(6):410-413. |
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| 作者姓名： | 陶敏莉 刘东志 周雪琴 |
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| 作者单位： | 天津大学化工学院,天津,300072;天津大学材料学院,天津,300072 |
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| 摘 要： | 本文以4-羟基1-萘甲醛为原料合成了新型萘基卟啉化合物meso-四(对十六烷氧基萘基)卟啉,该化合物未见文献报道,其结构通过1HNMR,IR和UV-Vis确定。同时,测定了其光谱性能,并与四苯基卟啉进行对比研究。研究表明长碳链萘基的引入增大了卟啉环的共轭程度,使其光学吸收波长与荧光发射波长发生红移。另外,本文对原料4-羟基1-萘甲醛及其醚化产物的合成进行了工艺条件优化。
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| 关 键 词： | 萘基卟啉 合成 光谱性能 4-羟基-1-萘甲醛 |
| 文章编号： | 1004-9533(2004)06-0410-04 |
| 修稿时间： | 2003年12月6日 |
Synthesis and Spectral Properties of Meso-tetra(p-hexadecyloxynaphthyl)porphyrin |
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| TAO Min-li,LIU Dong-zhi,ZHOU Xue-qin.Synthesis and Spectral Properties of Meso-tetra(p-hexadecyloxynaphthyl)porphyrin[J].Chemical Industry and Engineering,2004,21(6):410-413. |
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| Authors: | TAO Min-li LIU Dong-zhi ZHOU Xue-qin |
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| Affiliation: | (1.School of Chemical Engineering, Tianjin University, Tianjin 300072, China; 2.School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China |
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| Abstract: | A kind of novel compound meso-tetra(p-hexadecyloxynaphthyl) porphyrin 3 was synthesized from p-hydroxynaphthaldehyde and characterized by (()~1H) NMR, IR and UV-Vis spectra. The introduction of long carbon chain naphthyl group can enhance the conjugate degree of the porphyrin, and cause red-shift of the absorption spectra. The fluorescence spectrum exhibit that the maxium excitation wavelength red-shifts by 7 nm in 3 compared with that in tetraphenylporphyrin. The reaction condition of p-hydroxynaphthaldehyde and the corresponding long carbon chain ether were studied. |
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| Keywords: | naphthylporphyrin synthesis spectral property p-hydroxynaphthaldehyde |
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