Microstructure and martensitic transformations in a dual-phase α/β Cu-Zn alloy |
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Authors: | Y. F. Hsu W. H. Wang C. M. Wayman |
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Affiliation: | (1) the Department of Materials and Mineral Resources Engineering, National Taipei University of Technology, Taipei, Taiwan, 106, Republic of China;(2) the Institute of Materials Science and Engineering, National Taiwan University, Taipei, Taiwan, 107, Republic of China;(3) the Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 61801 Urbana, IL |
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Abstract: | The martensitic transformations in a dual-phase α/β Cu-Zn shape-memory alloy, containing 15 pct by volume of α particles, were studied during subcooling and deformation. The crystal structure and characteristics of the martensitic transformation of a dual-phase Cu-Zn alloy were found to be similar to those of a single-phase alloy. Both the thermal martensite formed by subcooling and the stress-induced martensite (SIM) formed by loading possessed an M9R long-period stacking-order (LPSO) structure, with internal stacking faults on the (001) basal plane. Upon subcooling, the α particles were deformed in order to accommodate the shape strain accompanying the martensitic transformation. Although most of them are deformed by slip, deformation twins have, nevertheless, been found in a few α particles. Upon loading, the SIM with an M9R structure nucleates and grows at a given temperature; subsequently, another martensite phase (α s ) possessing an fct structure is formed, with a shear developing on the basal plane of the initial M9R SIM during further loading. However, during unloading, both the α s and SIM are transformed and follow the reverse sequence back to the parent phase. However, some residual SIM and α s were found at zero load, due to a constraint effect of the deformed α particles and grain boundaries. The α s martensite may be formed by two intersecting plates of SIM or by advanced deformation on a single plate of SIM. In addition to the residual SIM and α s martensite, an SIM/α s lamellar martensite was found in the deformed specimen. |
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