| 一锅法合成N-烯丙基邻苯二甲酰亚胺 |
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| 引用本文： | 游胜勇,戴润英,陈衍华.一锅法合成N-烯丙基邻苯二甲酰亚胺[J].精细化工中间体,2011,41(6):31-33,76. |
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| 作者姓名： | 游胜勇 戴润英 陈衍华 |
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| 作者单位： | 1. 江西省科学院应用化学研究所,江西南昌,330029
2. 江西农业大学理学院,江西南昌,330047 |
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| 基金项目： | 江西省科技支撑计划项目(2010JX00379) |
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| 摘 要： | 以邻苯二甲酰亚胺和烯丙基氯为原料,采用一锅法合成,经红外和核磁氢谱表征,确定该产物为N-烯丙基邻苯二甲酰亚胺。考察原料配比、反应时间、反应温度、溶剂对产物收率的影响,得到优化反应条件:n(烯丙基氯)∶n(邻苯二甲酰亚胺)=1.5∶1,在60℃下反应12 h,N-烯丙基邻苯二甲酰亚胺的收率可高达88.5%。
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| 关 键 词： | N-烯丙基邻苯二甲酰亚胺 一锅法 邻苯二甲酰亚胺 烯丙基氯 |
One-pot Synthesis of N-Allylphthalimide |
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| YOU Sheng-yong
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DAI Run-ying
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CHEN Yan-hua.One-pot Synthesis of N-Allylphthalimide[J].Fine Chemical Intermediates,2011,41(6):31-33,76. |
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| Authors: | YOU Sheng-yong DAI Run-ying CHEN Yan-hua |
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| Affiliation: | 1(1.Institute of Applied Chemistry,Jiangxi Academy of Science,Nanchang 330029,China;2.College of Science,Jiangxi Agricultural University,Nanchang 330045,China) |
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| Abstract: | One-pot synthesis of N-allylphthalimide from phthalimide and allyl chloride was studied.Effects of feed ratio,reaction temperature,reaction time and solvent were investigated.Best results were obtained under conditions of the molar ratio of allyl chloride to phthalimide of 1.5:1,the temperature of 60℃ and the reaction time of 12 h,and the yield of N-allylphthalimide was 88.5%.The target product was identified with FT-IR and 1H NMR. |
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| Keywords: | N-allylphthalimide one-pot phthalimide allyl chloride |
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