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Effect of Rare Earth Oxides on the Microstructure and Microwave Dielectric Properties of CaO-MgO-Nb2Os-TiO2 System Ceramics
引用本文:WANG Hao CHEN Wen LIU Tao. Effect of Rare Earth Oxides on the Microstructure and Microwave Dielectric Properties of CaO-MgO-Nb2Os-TiO2 System Ceramics[J]. 武汉理工大学学报(材料科学英文版), 2005, 20(4): 83-86. DOI: 10.1007/BF02841290
作者姓名:WANG Hao CHEN Wen LIU Tao
作者单位:School of Materials Science and Engineering, Wuhan University of Technology, Wuhan, 430070, China
基金项目:Funded by the National Natural Science Foundation of China(50272044)
摘    要:La2O3 and SrO-doped CaO-MgO-Nb2O3-TiO2 system ceramics were prepared by solid-state ceramic technique.The microstructure and microwave dielectric properties of CaO-MgO-Nb2O5-TiO2-La2O3 cermics can be adjusted by varying the amount of La^3+ or Sr^2+ ions respectively.The replacement of Ca^2+ by La^3+ at A-site of the ceramics increases the quality factor Q value( at 7.6GHz)as well as the temperature coefficient of resonant frequency τf and decreases the dielectric constant εr and the substitution of Sr^2+ at A-site in this ceramics system exhibits opposite characteristics.The microwave properties of La^3+,Sr^2+-doped CaO-MgO-Nb2O5-TiO2 system ceramics depend on the degree of octahedral distortion inside materials.

关 键 词:微波介电陶瓷 稀土氧化物 钙钛矿 微观结构 氧化钙 氧化镁 五氧化二铌 二氧化钛
收稿时间:2005-04-08
修稿时间:2005-08-14

Effect of rare earth oxides on the microstructure and microwave dielectric properties of CaO−MgO−Nb2O5−TiO2 system ceramics
Wang Hao Ph D,Chen Wen,Liu Tao. Effect of rare earth oxides on the microstructure and microwave dielectric properties of CaO−MgO−Nb2O5−TiO2 system ceramics[J]. Journal of Wuhan University of Technology. Materials Science Edition, 2005, 20(4): 83-86. DOI: 10.1007/BF02841290
Authors:Wang Hao Ph D  Chen Wen  Liu Tao
Affiliation:(1) School of Materials Science and Engineering, Wuhan University of Technology, 430070 Wuhan, China
Abstract:La2O3 and SrO-doped CaO−MgO−Nb2O5−TiO2 system ceramics were prepared by solid-state ceramic technique. The microstructure and microwave dielectric properties of CaO−MgO−Nb2O5−TiO2−La2O3 ceramics can be adjusted by varying the amount of La3+ or Sr2+ ions respectively. The replacement of Ca2+ by La3+ at A-site of the ceramics increases the quality factor Q value (at 7.6 GHz) as well as the temperature coefficient of resonant frequency τ f and decreases the dielectric constant ɛ, and the substitution of Sr2+ at A-site in this ceramics system exhibits opposite characteristics. The microwave properties of La3+, Sr2+-doped CaO−MgO−Nb2O5−TiO2 system ceramics depend on the degree of octahedral distortion inside materials. Funded by the National Natural Science Foundation of China (50272044)
Keywords:perovskite  microwave dielectric ceramic  dielectric properties
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