| 微米螺旋碳纤维的电容特性 |
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| 引用本文： | 殷大根,朱亚波,杜勇,刘晓霞,刘章生. 微米螺旋碳纤维的电容特性[J]. 材料研究学报, 2012, 0(1): 73-77 |
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| 作者姓名： | 殷大根 朱亚波 杜勇 刘晓霞 刘章生 |
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| 作者单位： | 中国矿业大学材料科学与工程学院 |
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| 基金项目： | 国家大学生创新性实验计划;中国矿业大学创新能力提升基金2011XK07资助项目~~ |
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| 摘 要： | 用CVD法合成微米螺旋碳纤维（carbon microcoils,CMCs）,用硝酸和KOH等对其进行纯化和活化处理,用扫描电镜（SEM）、光学显微镜观察其形貌,用X-射线能谱仪分析反应后催化剂成分,并采用恒流充放电、循环伏安、交流阻抗等电化学方法分析CMCs超级电容器性能。结果表明,在50 mA·g-1电流密度条件下,初始CMCs产物的比电容为12.7 F·g-1,纯化处理后的比电容为41.4 F·g-1,活化处理后则达到111.1 F·g-1,为处理前的8.75倍。表明纯化特别是活化处理使其电容性能显著提高。
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| 关 键 词： | 无机非金属材料 微螺旋碳纤维 超级电容器 比电容 |
Electrochemical Capacitance Performance of Carbon Microcoils |
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| YIN Dagen ZHU Yabo DU Yong LIU Xiaoxia LIU Zhangsheng. Electrochemical Capacitance Performance of Carbon Microcoils[J]. Chinese Journal of Materials Research, 2012, 0(1): 73-77 |
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| Authors: | YIN Dagen ZHU Yabo DU Yong LIU Xiaoxia LIU Zhangsheng |
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| Affiliation: | YIN Dagen ZHU Yabo(**) DU Yong LIU Xiaoxia LIU Zhangsheng (School of Materials Science and Engineering,China University of Mining and Technology,Xuzhou 221116) |
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| Abstract: | Carbon microcoils（CMCs） were prepared by CVD,and then were purified and activated with nitric acid and KOH.The morphology of CMC samples with their catalyzer were characterized by means of scanning electron microscope,optical microscope and X-ray spectrometer,respectively. CMCs supercapacitors were characterized by charge-discharge,cyclic voltammetry（CV） and electrochemical impedance spectroscopy（EIS）.The results show that in the current density of 50 mA·g-1,the electrochemical capacity of no-disposed CMCs,purification CMCs and activation CMCs are 12.7 F·g-1,41.4 F·g-1 and 111.1 F·g-1（about 8.75 times before the disposed）,respectively.It can be concluded that the capacity of CMCs supercapacitors can be improved by purification and activation. |
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| Keywords: | inorganic non-metallic materials carbon microcoils supercapacitor electrochemical capacity |
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