The friction and wear characteristics and lubrication mechanism of imidazole phosphate ionic liquid |
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Authors: | Lin Zhang DaPeng Feng Bin Xu XuQing Liu WeiMin Liu |
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Affiliation: | (1) State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China;(2) Research Institute of Lanzhou Petrochemical Corporation, Lanzhou, 730000, China;(3) Graduate University of Chinese Academy of Sciences, Beijing, 100039, China |
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Abstract: | Several imidazole phosphate ionic liquids with varying carbon chain length have been synthesized at room temperature. Corrosion
characteristics and tribological properties of these synthesized ionic liquids were studied using four-ball friction and wear
testing machine. Its lubrication mechanism was also investigated by means of electron microscopy and X-ray photoelectron spectroscopy.
The experimental results showed that no corrosion was generated when the imidazole phosphate ionic liquid was applied to steel-steel
pair. Meanwhile, the imidazole phosphate showed excellent anti-wear and lubricating performances, its frictional performance
was related to the polarity of ionic liquids. It is suggested that the ionic liquids react with friction surface to form a
protective film of iron phosphate and result in reduction in friction and wear.
Supported by the National Natural Science Foundation of China (Grant Nos. 50721062 and 20533080) and the National Basic Research
Program of China (973 Program) (Grant No. 2007CB607606) |
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Keywords: | imidazole phosphate ionic liquids friction and wear lubrication mechanism |
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