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用黑铜泥制备砷酸钠和焦锑酸钠
引用本文:周兴,黄雁,王玉棉,赵忠兴. 用黑铜泥制备砷酸钠和焦锑酸钠[J]. 甘肃冶金, 2012, 0(1): 1-3
作者姓名:周兴  黄雁  王玉棉  赵忠兴
作者单位:[1]兰州理工大学材料科学与工程学院,甘肃兰州730050 [2]兰州理工大学甘肃省有色金属新材料重点实验室,甘肃兰州730050
摘    要:采用Na2S作浸出剂,在强碱性介质中浸出黑铜泥中的砷和锑,继续保持强碱性条件,用H2O2氧化浸出液,使砷、锑分离,分别制备砷酸钠和焦锑酸钠。浸出渣可以返回熔炼主流程。

关 键 词:黑铜泥  浸出  砷酸钠  焦锑酸钠

Preparation of Sodium Arsenate and Sodium Pyroantimonate from Black Copper Sludge
ZHOU XingI,HUANG Yan,WANG Yu-mian,',ZHAO Zhong-xing. Preparation of Sodium Arsenate and Sodium Pyroantimonate from Black Copper Sludge[J]. Gansu Metallurgy, 2012, 0(1): 1-3
Authors:ZHOU XingI  HUANG Yan  WANG Yu-mian    ZHAO Zhong-xing
Affiliation:l ( 1. College of Materials Science and Engineering, Lanzhou University of Tech. , Lanzhou 730050, China; 2. State Key Laboratory of Gansu Advanced Nonferrous Met',d Materi',ds, Lanzhou University of Tech. , Lanzhou ,730050, China)
Abstract:As and Sb in black copper sludge was leached at high pH values in the sodium sulfide solution. By maintaining strong alkaline conditions, As and Sb could be separated from the leaching solution using hydrogen peroxide as oxidant, and sodium arsenate and sodium pyroantimonate were obtained. Leach residue can return to the main smelting process.
Keywords:black copper sludge  leaching  sodium arsenate  sodium pyroantimonate
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