松香系列表面活性剂的合成和应用

介绍了国内外以松香及其衍生物为原料合成松香系列表面活性剂的主要方法，松香与环氧乙烷加成可得到松香聚氧乙烯非离子表面活性剂；松香聚氧乙烯和氯磺酸可合成阴离子表面活性剂；松香胺与环氧乙烷反应生成松香胺聚氧乙烯，再与氯乙醇季铵化得到阳离子表面活性剂；松香和二乙烯三胺反应，得到的酰胺与氯乙酸反应可合成两性表面活性剂。松香系列表面活性剂用途非常广泛，可作为乳化剂、洗涤剂、杀菌剂、润湿剂和降黏剂等，并对今后研究工作重点提出了建议和展望。

Synthesis and apply of rosin series surfactants

The main synthesis methods of rosin type surfactants from rosin and its derivatives in home and abroad were summarized. Rosin type nonionic surfactants of rosin polyethylene oxide was combined with rosin and ethylene oxide.Rosin type anionic surfactants were prepared from rosin polyethyleneoxide and chlorosulfonic acid. Rosin type cationic surfactants were prepared from ethylene chlorohydrin and abietyl amine polyethylene oxide that was synthesized with abietyl amine and ethylene oxide.Rosin type amphoteric surfactants were prepared from chloroacetic acid and acylamine that was synthesized with rosin and diethylenetriamine.Rosin type surfactants were used widly as emulsifying agent,detergent,germicide,wetting agent,emulsion-viscosity reduction and so on. Some prospections are given for research work of resin type surfactants in future.