Spiro Linkage as an Alternative Strategy for Promising Nonfullerene Acceptors in Organic Solar Cells

This work focuses on developing diketopyrrolopyrrole (DPP)‐based small molecular nonfullerene acceptors for bulk heterojunction (BHJ) organic solar cells. The materials, SF‐DPP s, have an X‐shaped geometry arising from four DPP units attached to a spirobifluorene (SF) center. The spiro‐dimer of DPP‐fluorene‐DPP is highly twisted, which suppresses strong intermolecular aggregation. Branched 2‐ethylhexyl (EH), linear n‐octyl (C8), and n‐dodecyl (C12) alkyl sides are chosen as substituents to functionalize the N,N‐positions of the DPP moiety to tune molecular interactions. SF‐DPPEH , the best candidate in SF‐DPP s family, when blended with poly(3‐hexylthiophene) (P3HT) showed a moderate crystallinity and gives a J_sc of 6.96 mA cm^?2, V_oc of 1.10 V, a fill factor of 47.5%, and a power conversion efficiency of 3.63%. However, SF‐DPPC8 and SF‐DPPC12 exhibit lower crystallinity in their BHJ blends, which is responsible for their reduced J_sc. Coupling DPP units with SF using an acetylene bridge yields SF‐A‐DPP molecules. Such a small modification leads to drastically different morphological features and far inferior device performance. These observations demonstrate a solid structure–property relationship by topology control and material design. This work offers a new molecular design approach to develop efficient small molecule nonfullerene acceptors.