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炭黑填充导电橡胶的温度传感器灵敏系数
引用本文:黄英,刘平,廉超,刘秀梅,蒋红生.炭黑填充导电橡胶的温度传感器灵敏系数[J].复合材料学报,2012,29(3):30-35.
作者姓名:黄英  刘平  廉超  刘秀梅  蒋红生
作者单位:1. 合肥工业大学电子科学与应用物理学院, 合肥 230009;2. 中国科学院合肥智能机械研究所, 合肥 230031;3. 中国科学技术大学自动化系, 合肥 230027
基金项目:国家自然科学基金,国家高技术研究发展计划
摘    要:以通用有效介质理论为基础,给出了炭黑填充导电橡胶(导电炭黑/橡胶)的温度传感器电阻-温度计算模型。利用该模型得出材料的灵敏系数计算公式,并结合形变和电阻率的变化对正电阻-温度特性(PTCR)的影响分析材料的灵敏系数特性。结果表明:在炭黑分布均匀、体积分数在渗流体积分数附近等条件下,电阻-温度计算模型与实验吻合,表现出一致的PTCR变化规律。导电炭黑/橡胶的PTCR效应主要源于基体膨胀导致炭黑体积分数的稀释作用,若炭黑体积分数在渗流区,导电炭黑/橡胶的灵敏系数为280~420;当炭黑体积分数在传导区时,其灵敏系数为32.5~62.0。导电炭黑/橡胶的PTCR效应是热-形变与形变-电导过程的乘积效应,导电炭黑/橡胶的灵敏系数高,但其体积膨胀系数低,使材料的电阻温度系数较低。

关 键 词:复合材料  温度特性  灵敏系数  炭黑  导电橡胶  柔性触觉传感器  
收稿时间:2011-06-26

Sensitive coefficient of temperature sensor based on conductive rubber filled by carbon black
HUANG Ying , LIU Ping , LIAN Chao , LIU Xiumei , JIANG Hongsheng.Sensitive coefficient of temperature sensor based on conductive rubber filled by carbon black[J].Acta Materiae Compositae Sinica,2012,29(3):30-35.
Authors:HUANG Ying  LIU Ping  LIAN Chao  LIU Xiumei  JIANG Hongsheng
Affiliation:1. School of Electronic Science & Applied Physics, Hefei University of Technology, Hefei 230009, China;2. Institute of Intelligence Machines, Chinese Academy of Sciences, Hefei 230031, China;3. Department of Automation, University of Science and Technology of China, Hefei 230027, China
Abstract:A formula of positive temperature coefficient of resistance (PTCR) of conductive rubber filled by carbon black (CB) used for temperature sensor was given by general effective media theory. The sensitive coefficient was analyzed by the equation of sensitive coefficient deduced from the formula of PTCR and the impact of the strain and resistivity on PTCR effect. The formula of PTCR is consonant with the experimental results well when the CB is dispersed homogeneously and the volume fraction of CB is close to the critical threshold. A dilution of the volume fraction of CB due to the volume expansion of the composites has a significant influence on PTCR effect. When the volume fraction of CB is within the percolation zone, the scope of sensitive coefficient is from 280 to 420. If the volume fraction of CB is within the conductive zone, the scope of sensitive coefficient is from 32.5 to 62. PTCR effect is a complex process of the heat-deformation and the deformation-conductivity. Due to the coefficient of cubical expansion is low, conductive carbon black/rubber has high sensitive coefficient, but the value of PTCR
Keywords:composite  temperature characteristic  sensitive coefficient  carbon black  conductive rubber ~ flexibletactile sensor
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