Novel Thermally-Accessible Structural Changes of Chiral and Some Related Cu(ll) Complexes |
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作者姓名: | Satoshi Ehara Takashiro Akitsu |
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作者单位: | Department of Chemistry, Faculty of Science, Tokyo University of Science, Tokyo 162-8601, Japan |
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摘 要: | A mononuclear chiral copper(ll) complex, [Cu(RRchxn)2(C(CN)3)2]'H20 (RRchxn = (1R, 2R)-diaminocyclohexane) (RRchxnH), and its deuterated compound, [Cu(RRchxn)2(C(CN)3)z].D20 (RRchxnD), and their isomers, [Cu(trchxn)2(C(CN)3)2]'H20 (trchxn = trans-l,2-diaminocyclohexane) (trchxnH) and [Cu(trchxn)2(C(CN)3)2]'D20 (trchxnD) have been prepared and characterized by means of 1R (infrared), electronic, and CD (circular dichroism) spectra, magnetic susceptibility, and variable-temperature X-ray crystallography as single crystals or powder. Interestingly, depending on grain size of samples, RRchxnH exhibits the monoclinic form and the orthorhombic form, which are distinguished by systematic absence and powder XRD (X-ray diffraction) patterns clearly. Although single crystals did not exhibit phase transition, powder XRD patterns of RRchxnH and weakly hydrogen bonded RRchxnD emerged low-temperature phase of monoclinic in the orthorhombic patterns only around 200-220 K. However, as a control, powder XRD patterns of both trchxnH and trchxnD did not exhibit such phase transition clearly.
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关 键 词: | Cu(Ⅱ)配合物 粉末X射线衍射 结构变化 手性 X-射线晶体学 残疾人 铜(II)配合物 衍射图案 |
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