| 含MCM-22分子筛催化剂的裂化反应性能研究 |
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| 引用本文： | 马广印,刘中清,傅军,何鸣元.含MCM-22分子筛催化剂的裂化反应性能研究[J].石油炼制与化工,2005,36(11):11-15. |
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| 作者姓名： | 马广印 刘中清 傅军 何鸣元 |
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| 作者单位： | 1. 中国石油化工股份有限公司,北京,100029
2. 石油化工科学研究院 |
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| 基金项目： | 国家重大基础研究规划项目“石油炼制与基本有机化学品合成的绿色化学”,G2000480001. |
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| 摘 要： | 研究了ZSM-5，Beta，MCM-22分子筛分别作为FCC催化剂添加组分的性能。结果表明，催化剂中含MCM-22的汽油和柴油产率高于含ZSM-5，与含Beta相当；气体产物的产率低于ZSM-5，高于Beta而焦炭产率比二者都高。并且发现，含MCM-22的氢转移活性比含ZSM一5和含Beta高；裂化机理比率（CMR）低于ZSM-5．与Beta相当，说明在催化裂化反应中MCM-22晶体表面的12MR孔穴起重要作用。MCM-22的催化裂化反应性能介于ZSM-5和Beta之间，更接近于Beta．
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| 关 键 词： | 催化裂化 催化剂 分子筛 收率 |
| 收稿时间： | 2005-04-08 |
| 修稿时间： | 2005-05-17 |
CRACKING PERFORMANCE OF CATALYST WITH ZEOLITE MCM-22 |
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| Ma Guangyin,Liu Zhongqing,Fu Jun,He Mingyuan.CRACKING PERFORMANCE OF CATALYST WITH ZEOLITE MCM-22[J].Petroleum Processing and Petrochemicals,2005,36(11):11-15. |
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| Authors: | Ma Guangyin Liu Zhongqing Fu Jun He Mingyuan |
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| Affiliation: | 1. SINOPEC, Beijing 100029; 2. Research Institute of Petroleum Processing |
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| Abstract: | The performance of zeolite ZSM-5, Beta, and MCM-22 as FCC catalyst additive components was investigated. The results showed that the catalyst with MCM-22 yielded more naphtha, LCO and coke, less gas comparing with the catalyst with ZSM-5, and less naphtha and LCO, more coke and gas comparing with the catalyst with Beta. While the cracking mechanism ratio (CMR) of MCM-22 was lower than that of ZSM-5, similar to that of Beta, which meant that the 12MR cups on the crystal of MCM-22 played an important role in catalytic cracking reaction. The performance of MCM-22 in cracking reaction was between that of ZSM-5 and Beta, and was close to that of Beta. |
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| Keywords: | catalytic cracking catalyst molecular sieve yield |
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