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Study of the Catalytic Ozonation of Humic Substances in Water and Their Ozonation Byproducts
Authors:R. Gracia  J.L. Aragües  J.L. Ovelleiro
Abstract:It is shown that using transition metals, especially Mn(II) and Ag(I), during ozonation of humic substances in water allows important reductions in the content of organic matter. Characterization of the organic compounds resulting from ozonation was made by concentrating the sample through liquid-liquid extraction or derivation with PFBOA.HCl, along with the GC/MS and GC/ECD techniques. In total, 110 different organic compounds were identified using GC/MS; mainly carboxylic acids, aromatics, hydrocarbons, aldehydes, ketones, and furan-carboxylic acids. The percentages of elimination or formation levels reached during ozonation are discussed.
Keywords:Ozone  Ozonation  Drinking Water  Humic Acids  Ozone Byproducts  Derivatization  Inorganic Metal Salt Catalysts  Manganese  Silver
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