| 微波辐射法催化合成苯甲酸苄酯的研究 |
| |
| 引用本文： | 边延江,刘会明,刘胜军,孔洁,宋艳芳.微波辐射法催化合成苯甲酸苄酯的研究[J].精细石油化工,2004(6):41-43. |
| |
| 作者姓名： | 边延江 刘会明 刘胜军 孔洁 宋艳芳 |
| |
| 作者单位： | 廊坊师范学院化学系,河北,廊坊,065000 |
| |
| 基金项目： | 廊坊师范学院科学研究项目(No．200308) |
| |
| 摘 要： | 以苯甲酸和苄醇为原料,SnCl4·5H2O为催化剂,在微波辐射下合成了苯甲酸苄酯。最佳反应条件:醇酸摩尔为5:1,催化剂用量1.2g/0.04mol苯甲酸,微波辐射功率464w,辐射时间6min,酯化率82.6%。
|
| 关 键 词： | 微波辐射 苯甲酸 苄醇 四氯化锡 苯甲酸苄酯 催化 |
| 修稿时间： | 2003年8月23日 |
STUDY ON CATALYTIC SYNTHESIS OF BENZYL BENZOATE UNDER MICROWAVE IRRADIATION |
| |
| Bian Yanjiang,Liu Huiming,Liu Shengjun,Kong Jie and Song Yanfang.STUDY ON CATALYTIC SYNTHESIS OF BENZYL BENZOATE UNDER MICROWAVE IRRADIATION[J].Speciality Petrochemicals,2004(6):41-43. |
| |
| Authors: | Bian Yanjiang Liu Huiming Liu Shengjun Kong Jie and Song Yanfang |
| |
| Abstract: | The benzyl benzoate was directly synthesized from benzoic acid(BA) and benzyl alcohol with SnCl4·5H2O as catalyst under microwave irradiation. The optimal reaction conditions were as follows: microwave power 464 W, irradiation time 6 min, the molar ratio of alcohol to acid 5:1, SnCl4·5H2O 1. 2 g/0. 04 mol BA, the yield was up to 82. 6%. |
| |
| Keywords: | microwave irradiation benzoic acid benzyl alcohol tin tetrachloride benzyl benzoate catalysis |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
