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RGO/MgO hybrid nanocomposites with high specific capacitance
Authors:Pradip Sekhar Das  Suvajit Bakuli  Indranil Biswas  Awadesh Kumar Mallik  Arjun Dey  Smita Mukherjee  Jiten Ghosh  Anoop Kumar Mukhopadhyay
Affiliation:1. Advanced Mechanical and Materials Characterization Division, CSIR-Central Glass and Ceramic Research Institute (CGCRI), Kolkata 700032, India;2. Material Characterization and Instrumentation Division, CSIR-Central Glass and Ceramic Research Institute (CGCRI), Kolkata 700032, India;3. Bioceramics and Coating Division, CSIR-Central Glass and Ceramic Research Institute (CGCRI), Kolkata 700032, India;4. Thermal Systems Group, ISRO Satellite Centre, Vimanapura Post, Bangalore 560017, India
Abstract:A scalable, cost effective synthesis of reduced graphene oxide (RGO)-magnesium oxide (MgO) hybrid nanocomposite (RGOMOHNC) is reported in the present work. The process involves an in-situ sonication method in aqueous medium at room temperature e.g., 30 °C. The as synthesized graphene oxide (GO) and RGOMOHNC powders are characterized by the XRD, FESEM, TEM, FTIR, RS and XPS techniques. The results indicate that in-situ growth of 20–30 nm MgO nanoparticles effectively increases the graphitic nature of the layered RGO microstructure. The experimentally measured cyclic voltammetry (CV) plots show that the specific capacitance of the RGOMOHNC powders is three orders of magnitude higher than that of the GO powders. A mechanism of RGOMOHNC formation has been proposed.
Keywords:Nanocomposites  RGO/MgO  Spectroscopy  Electrodes
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