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NP-10/硝酸钠水溶液体系的相行为与流变性
引用本文:冯尚华,王红霞,张高勇,谢新玲. NP-10/硝酸钠水溶液体系的相行为与流变性[J]. 精细化工, 2003, 20(12): 738-741
作者姓名:冯尚华  王红霞  张高勇  谢新玲
作者单位:中国日用化学工业研究院,山西,太原,030001
基金项目:国家自然科学基金重点资助项目(No.20233010)~~
摘    要:研究了浓度为0.02mol/L的硝酸钠水溶液中非离子表面活性剂NP-10的相行为与流变学性质。随NP-10质量分数的增加,体系中依次可以形成胶束,六角状、立方状和层状液晶以及反胶束。六角状和立方状液晶的流变学性质可以用Maxwell模型说明。用已经验证的经验方程对层状液晶的流变学特征做出了表述。

关 键 词:表面活性剂  溶致液晶  流变性  Maxwell方程
文章编号:1003-5214(2003)12-0738-04

Phase Behavior and Rheological Properties of NP-10/Brine
FENG Shang-hua,WANG Hong-xia,ZHANG Gao-yong,XIE Xin-ling. Phase Behavior and Rheological Properties of NP-10/Brine[J]. Fine Chemicals, 2003, 20(12): 738-741
Authors:FENG Shang-hua  WANG Hong-xia  ZHANG Gao-yong  XIE Xin-ling
Abstract:The phase behavior and rheological properties of NP-10 in 0.02 mol/L aqueous NaNO_3 solution were investigated.It was demonstrated that micelle,hexagonal,cubic,and lamellar liquid crystals and inverse micelle were formed successively in the same system as the mass fraction of NP-10 increased.The rheological properties of hexagonal and cubic liquid crystals are illustrated by Maxwell model,and the property of lamellar mesophase is explained by an empirical formula which has been validated in other cases.
Keywords:surfactant  lyotropic liquid crystal  rheological property  Maxwell equation
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