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Influences of Nd~(3+) doping on structure and electrochemical performance of layered Li_(1.05)V_3O_8
引用本文:刘丽英,张海燕,翟玉春,田彦文.Influences of Nd~(3+) doping on structure and electrochemical performance of layered Li_(1.05)V_3O_8[J].中国稀土学报(英文版),2011,29(2):150-154.
作者姓名:刘丽英  张海燕  翟玉春  田彦文
作者单位:LIU Liying(School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China;McNair Technology Co. Ltd., Dongguan 523800, China);ZHANG Haiyan(School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China);ZHAI Yuchun,TIAN Yanwen(Institute of Materials and Metallurgy, Northeastern University, Shenyang 110004, China)
基金项目:Project supported by Guangdong Department of Education Fund (LYM09061)
摘    要:Nd3+-doped Li1.05V3O8 was synthesized by liquid-state reactions combined calcination.The influences of Nd3+ doping on physical and electrochemical performances of Li1.05V3O8 were investigated using X-ray diffraction (XRD),cyclic voltammograms,a.c.impedance and galvanostatic charge-discharge tests,etc.Results indicated that Nd3+-doped products had well developed crystal structure of layered LiV3O8 and uniform particle size distribution.Nd3+ doping with a proper amount improved the initial discharge capacity,discharge voltage and ion conductivity of the cathode material to some extent.Nd3+ did not participate in the electrochemical reactions and was beneficial to stability of the crystal structure during cycling.

关 键 词:neodymium  doping  LiV3O8  cathode  material  lithium-ion  battery  rare  earths

Influences of Nd3+ doping on structure and electrochemical performance of layered Li1.05V3O8
LIU Liying,ZHANG Haiyan,ZHAI Yuchun,TIAN Yanwen.Influences of Nd3+ doping on structure and electrochemical performance of layered Li1.05V3O8[J].Journal of Rare Earths,2011,29(2):150-154.
Authors:LIU Liying  ZHANG Haiyan  ZHAI Yuchun  TIAN Yanwen
Affiliation:LIU Liying 1,2,ZHANG Haiyan 1,ZHAI Yuchun 3,TIAN Yanwen 3 (1.School of Materials and Energy,Guangdong University of Technology,Guangzhou 510006,China,2.McNair Technology Co.Ltd.,Dongguan 523800,3.In- stitute of Materials and Metallurgy,Northeastern University,Shenyang 110004,China)
Abstract:Nd3+-doped Li1.05V3O8 was synthesized by liquid-state reactions combined calcination.The influences of Nd3+ doping on physical and electrochemical performances of Li1.05V3O8 were investigated using X-ray diffraction (XRD),cyclic voltammograms,a.c.impedance and galvanostatic charge-discharge tests,etc.Results indicated that Nd3+-doped products had well developed crystal structure of layered LiV3O8 and uniform particle size distribution.Nd3+ doping with a proper amount improved the initial discharge capacity,...
Keywords:neodymium  doping  LiV3O8  cathode material  lithium-ion battery  rare earths  
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