Influence of the annealing in nitrogen atmosphere on the XRD, EDX, SEM and electrical properties of chemical bath deposited CdSe thin films

The influence of annealing in nitrogen atmosphere on the structure, optical and electrical properties of cadmium selenide (CdSe) thin films deposited by chemical bath deposition (CBD) onto glass substrates was studied. The samples were annealed in nitrogen atmosphere at various temperatures. A transition from metastable nanocrystalline cubic to stable polycrystalline hexagonal phase has been observed after annealing. The as-deposited CdSe thin films grow in the nanocrystalline cubic phase with optical band gap 1.93 eV. The electrical resistivity of the thin films has been measured in order of 10⁶ Ω cm. The activation energy of the samples has been found to be 0.26–0.19 eV at low temperature region, and 0.36–0.56 eV at high temperature region. It was also found that the activation energy and the resistivity of the films decrease with the increasing annealing temperature.