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Investigation of the defect density in ultra-thin Al2O3 films grown using atomic layer deposition
Authors:Yadong Zhang  Dragos SegheteAziz Abdulagatov  Zachary GibbsAndrew Cavanagh  Ronggui YangSteven George  Yung-Cheng Lee
Affiliation:
  • a Department of Mechanical Engineering, University of Colorado, Boulder, CO 80309, USA
  • b Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309, USA
  • c Department of Chemical and Biological Engineering, University of Colorado, Boulder, CO 80309, USA
  • d Department of Physics, University of Colorado, Boulder, CO 80309, USA
  • Abstract:The film perfection in terms of pinhole defect densities of ultra-thin Al2O3 grown by atomic layer deposition (ALD) has been quantitatively characterized. A significant defect density reduction from ~ 1.2 × 105/cm2 to ~ 90/cm2 was demonstrated for 2 nm-thick Al2O3 by using an ALD tungsten (W) buffer layer on the nickel (Ni) substrate. The reason for the defect reduction was attributed to efficient nucleation of ALD Al2O3 on ALD W. The effect of the buffer layer becomes less essential as the Al2O3 thickness increases, where the substrate surface physical conditions such as particle contamination become the main cause for defects.
    Keywords:Defect  Ultra-thin Al2O3  Atomic layer deposition  Buffer layer  Nucleation  Electroplating
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