The synergistic mechanism of solvent extraction of gold in HCI media with TOA and TOPO |
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Authors: | Yang Tianzu Shui Chenjing and Bin Wanda |
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Affiliation: | (1) Department of Nonferrous Metallurgy, Central South University of Technology, 410083 Changsha, China |
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Abstract: | The mechanism of synergistic extraction of gold in HCl media was researched with tri-n-octyl amine(TOA) and tri-n-octyl phospine
oxide(TOPO). It was determined that the composition of synergistic extract is (TOAHTOPO) AuCl4; the constant of synergistic extracting equilibrium is 109.20; and the synergistic reaction is exothermic with − 17.187 kJ/K· mol of ΔH
298. The extraction mechanism was also studied by the IR-spectra and UV-spectra. It is found that the extraction mechanism belongs
to ion-association type.
Synopsis of the first author Yang Tianzu, professor, born in April 1958, majoring in the metallurgy of precious metals and coordination chemistry in hydrometallurgy. |
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Keywords: | gold synergistic extraction hydrochloric acid media mechanism of extraction |
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