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合成富铟铁酸锌中铟的硫酸浸出行为研究
引用本文:张琳叶,莫家梅,黎铉海,刘晓彬,杨景芳,潘柳萍,梁信源,魏光涛.合成富铟铁酸锌中铟的硫酸浸出行为研究[J].金属矿山,2013,42(11):84-87.
作者姓名:张琳叶  莫家梅  黎铉海  刘晓彬  杨景芳  潘柳萍  梁信源  魏光涛
作者单位:广西大学化学化工学院
基金项目:* 广西自然科学基金项目(编号:2012GXNSFAA053210),广西大学科研基金项目(编号:XJZ120273),广西大学实验室建设与实验教学改革项目(编号:20120329),广西大学“大学生创新创业训练计划”自治区级创新训练项目(编号:1301045),广西大学大学生实验技能和科技创新能力训练项目(编号:SYJN20120337)。
摘    要:为了给富铟铁酸锌中铟的高效回收提供参考,以铟浸出率为评价指标,研究了人工合成富铟铁酸锌硫酸浸出的工艺条件及其动力学模型。结果表明:合成富铟铁酸锌的粒度在0150~0045 mm范围内变化对铟浸出率影响较小,浸出反应温度、浸出时间、搅拌速度对铟浸出率影响较大,较理想的浸出反应温度为85 ℃、浸出时间为60 min、搅拌速度为300 r/min;该浸出反应符合未反应缩核模型,其表观活化能Ea为53555 kJ/mol。

关 键 词:富铟铁酸锌  酸浸铟  浸出动力学  

Study on the Leaching Behaviror of Sulphuric Acid of Indium from Synthesis Indium-bearing Zinc Ferrite
Zhang Linye,Mo Jiamei,Li Xuanhai,Liu Xiaobin,Yang Jingfang,Pan Liuping,Liang Xinyuan,Wei Guangtao.Study on the Leaching Behaviror of Sulphuric Acid of Indium from Synthesis Indium-bearing Zinc Ferrite[J].Metal Mine,2013,42(11):84-87.
Authors:Zhang Linye  Mo Jiamei  Li Xuanhai  Liu Xiaobin  Yang Jingfang  Pan Liuping  Liang Xinyuan  Wei Guangtao
Affiliation:School of Chemistry and Chemical Engineering,Guangxi University
Abstract:In order to provide reference for efficiently recovery of indium from Indium-bearing zinc ferrite,the processing conditions for leaching of synthesis indium-bearing zinc ferrite in sulphuric acid and its leaching kinetics model were studied with the indium leaching rate as index. The results showed that IBZF within range of 0.150 ~ 0.045 mm in particle size had little effect on indium,but leaching temperature,leaching time and stirring speed greatly impacted on leaching rate of indium. The ideal leaching temperature is 85 ℃,leaching time is 60 min,and stirring speed is 300 r/min. The indium leaching reaction of IBZF in sulfuric acid fits the un-reacted shrinking core model with the apparent activation energy Ea of 53.555 kJ/mol.
Keywords:Indium-bearing zinc ferrite  Indium leaching by acid  Kinetics of leaching
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