臭氧助浸提高石煤中钒浸出率

为了确定湖北某含钒石煤的合适开发利用工艺,以该矿的原生石煤、风化石煤、原生石煤焙烧渣为浸出对象,研究了臭氧对这些试样硫酸酸浸提钒效率的影响。结果表明:①通入臭氧可提高原生石煤、石煤焙烧渣和风化石煤的钒浸出率,且随着臭氧流量的增大钒浸出率上升。②提高浸出温度有助于增强臭氧的助浸效果。③提高H2SO4溶液浓度有助于强化臭氧对原生石煤中钒的浸出效果,但臭氧对石煤焙烧渣和风化石煤却没有这样的强化效果。④-200目占78%的试样100 g在H2SO4溶液浓度为25%、液固比为5∶1、搅拌速度为600 r/min、浸出温度为90℃、浸出时间为2 h情况下,通入25 L/h的臭氧与不通入臭氧相比,可将原生石煤、风化石煤、石煤焙烧渣的钒浸出率从6.86%、51.81%和24.24%提高至23.02%、61.05%和28.11%,提高的幅度分别达16.16、9.24、3.87个百分点。

Improving Vanadium Leaching Rate from Stone Coal Aided by Ozone

Engineering & Research Institute Co.,Ltd.of Nonferrous Metallurgy，Changsha 410011，China Effects of ozone on vanadium extraction efficiency with sulfuric acid leaching were studied using raw stone coal，weathering stone coal and roasted residue of raw stone coal as the subject，in order to find an appropriate exploitation and utilization technology for vanadium extraction.The results indicated that：①Vanadium leaching rate from stone coal，roasted residue and weathering stone coal was increased by ozone addition and increased with flow rate of ozone.②Ozone-aided efficiency was increased by raising the temperature.③Increasing concentration of sulfuric acid solution improved vanadium leaching efficiency of ozone from stone coal，while not the same for roasted residue of stone coal and weathering stone coal.④Vanadium leaching rate of stone coal ore，weathering stone coal and roasted residue was increased to 23.02%，61.05%，28.11% from 6.86%，51.81% and 24.24% respectively by addition of 25 L/h ozone flow，with 100 g sample at grain fineness of 78% passing 0.074 mm，sulfuric acid solution concentration of 25%，liquid to solid ratio of 5∶1，stirring speed of 600 r/min，at leaching temperature of 90 ℃ for 2 h，compared with that of without ozone,increased range reach 16.16，9.24 and 3.87 precentage points respectively.