| 加氢尾油光氯化法合成氯化石蜡的研究 |
| |
| 引用本文： | 张跃,何淑芹,刘建武,严生虎,沈介发. 加氢尾油光氯化法合成氯化石蜡的研究[J]. 精细石油化工, 2007, 24(3): 31-34 |
| |
| 作者姓名： | 张跃 何淑芹 刘建武 严生虎 沈介发 |
| |
| 作者单位： | 江苏工业学院精细化工研究所,江苏,常州,213164;中国石油吉林石化公司科技规划处,吉林,吉林,132021 |
| |
| 摘 要： | 以加氢尾油、氯气为原料,浓硫酸为酸洗剂,白土为吸附剂,通过光氯化法合成了氯化石蜡-52。物料配比为m(硫酸):m(白土):m(加氢尾油)=8:6:100,酸洗处理的温度为100℃,酸洗时间为2 h,静置时间为1 h。白土吸附温度为120℃,吸附时间为2 h,静置时间为2 h。氯化反应温度控制在70～80℃,氯化石蜡产物含量≥52%。
|
| 关 键 词： | 加氢尾油 氯气 光氯化 |
| 收稿时间： | 2006-09-11 |
| 修稿时间： | 2006-09-112007-03-13 |
STUDY ON PHOTOCHEMICAL CHLORINATION OF HYDROCRACKING TAIL OIL TO SYNTHESIZE CHLOROPARAFFIN |
| |
| Zhang Yue,He Shuqin,Liu Jianwu,Yan Shenghu,Shen Jiefa. STUDY ON PHOTOCHEMICAL CHLORINATION OF HYDROCRACKING TAIL OIL TO SYNTHESIZE CHLOROPARAFFIN[J]. Speciality Petrochemicals, 2007, 24(3): 31-34 |
| |
| Authors: | Zhang Yue He Shuqin Liu Jianwu Yan Shenghu Shen Jiefa |
| |
| Affiliation: | (1. The Research Institute of Fine Chemical Engineering,J iangsu Polytechnic University,Changzhou 213164, Jiangsu, China;2. Department of Science and Technology,Jilin Petrochemical Company of PrtroChina ,Jilin 132021, Jilin, China |
| |
| Abstract: | Chlorinated paraffin-52 was prepared by photochemical chlorination of hydrocracking tail oil with chorine,using H_2SO_4 as acid washing solution,bentonite as absorbent.The optimal conditions were found as follows:m(H_2SO_4)/m(bentonite)/m(chloroparaffin)=8:6:100,acid washing temperature 100℃,washing 2 h,keeping at static condition for 1 h,bentonite absorption temperature 120℃,absorbing 2 h,keeping at static condition for 2 h,chlorination reaction temperature from 70 to 80℃.Under these conditions,chloroparaffin could be obtained with 52% content. |
| |
| Keywords: | hydrocracking tail oil chorine photochemical chlorination |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
