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Fullerene photoelectrochemical solar cells
Authors:S Licht  O Khaselev  P A Ramakrishnan  D Faiman  E A Katz  A Shames  S Goren
Affiliation:aDepartment of Chemistry, Technion - Israel Institute of Technology, Haifa, 32000, Israel;bThe Ben-Gurion National Solar Energy Center, The Jacob Blaustein Institute For Desert Research, Ben-Gurion University Of the Negev, Sede Boqer Campus, Sede Boqer, 84990, Israel;cDepartment of Physics, Ben-Gurion University, Beer-Sheva, 84105, Israel
Abstract:The photoelectrochemistry of single crystal C60 and fullerene photoelectrochemical solar cells is studied. Illuminated and immersed, C60 is shown to drive oxidation of several solution-phase redox couples. Utilization of a photoelectrochemical solid/liquid junction, rather than solid-state photovoltaic junction, improves the observed photocurrent. Utilization of a single crystal, rather than a polycrystalline film, of C60 decreases dark current to the extent that light-driven charge transfer dominates. The spectral response and current-voltage behaviour in several electrolytes is studied. A low-power fullerene photoelectrochemical solar cell, utilizing a regenerative polyiodide and ferri/ferrocyanide redox couple, is demonstrated.
Keywords:Fullerene  Solar cell  Photoelectrochemistry
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