Fullerene photoelectrochemical solar cells |
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Authors: | S Licht O Khaselev P A Ramakrishnan D Faiman E A Katz A Shames S Goren |
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Affiliation: | aDepartment of Chemistry, Technion - Israel Institute of Technology, Haifa, 32000, Israel;bThe Ben-Gurion National Solar Energy Center, The Jacob Blaustein Institute For Desert Research, Ben-Gurion University Of the Negev, Sede Boqer Campus, Sede Boqer, 84990, Israel;cDepartment of Physics, Ben-Gurion University, Beer-Sheva, 84105, Israel |
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Abstract: | The photoelectrochemistry of single crystal C60 and fullerene photoelectrochemical solar cells is studied. Illuminated and immersed, C60 is shown to drive oxidation of several solution-phase redox couples. Utilization of a photoelectrochemical solid/liquid junction, rather than solid-state photovoltaic junction, improves the observed photocurrent. Utilization of a single crystal, rather than a polycrystalline film, of C60 decreases dark current to the extent that light-driven charge transfer dominates. The spectral response and current-voltage behaviour in several electrolytes is studied. A low-power fullerene photoelectrochemical solar cell, utilizing a regenerative polyiodide and ferri/ferrocyanide redox couple, is demonstrated. |
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Keywords: | Fullerene Solar cell Photoelectrochemistry |
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