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硫酸浸取法从高钛型高炉渣富钛产物中提取钛
引用本文:孙红娟,周国彪,彭同江,吴逍,何思祺.硫酸浸取法从高钛型高炉渣富钛产物中提取钛[J].矿冶,2015,24(3):54-58.
作者姓名:孙红娟  周国彪  彭同江  吴逍  何思祺
作者单位:西南科技大学固体废物处理与资源化教育部重点实验室,四川 绵阳 621010;西南科技大学矿物材料及应用研究所,四川绵阳621010
基金项目:固体废物处理与资源化教育部重点实验室资助课题(13zxgk06)
摘    要:以攀西地区高钛型高炉渣经磁选、硫化焙烧-水浸、盐洗处理后所获的富钛产物为原料,采用稀硫酸浸出法提取其中的钛组分.考察了硫酸质量分数、温度、酸渣质量比和时间对钛浸取率的影响.采用XRF和XRD对富钛产物和酸浸渣的化学成分与物相组成进行了研究.结果表明,富钛产物中Ti02含量超过35%,主要以无定型水合氧化钛和钙钛矿形式存在;提取钛的最佳条件为:硫酸质量分数60%,温度160℃,酸渣质量比(1.25~1.5):1,时间2.5h,Ti02浸取率可达90%以上,且纯度较高;酸解过程中,无定型水合氧化钛最先溶出,其次是钙钛矿,最后是部分透辉石.该工艺具有用酸浓度低、酸解时间短、Ti02浸取率高等特点,对高钛型高炉渣资源化利用具有重要的意义.

关 键 词:含钛高炉矿渣  富钛产物  稀硫酸  钛组分
收稿时间:2014/7/28 0:00:00
修稿时间:8/2/2014 12:00:00 AM

Recovery of titanium from rich-titanium product prepared from high Ti-bearing blast furnace slag by sulfuric acid leaching
SUN Hongjuan,ZHOU Guobiao,PENG Tongjiang,WU Xiao and HE Siqi.Recovery of titanium from rich-titanium product prepared from high Ti-bearing blast furnace slag by sulfuric acid leaching[J].Mining & Metallurgy,2015,24(3):54-58.
Authors:SUN Hongjuan  ZHOU Guobiao  PENG Tongjiang  WU Xiao and HE Siqi
Affiliation:Key Laboratory of Solid Waste Treatment and Resource Recycle, Southwest University of Science and Technology, Ministry of Education; Institute of Mineral Materials & Application, Southwest University of Science and Technology,Key Laboratory of Solid Waste Treatment and Resource Recycle, Southwest University of Science and Technology, Ministry of Education; Institute of Mineral Materials & Application, Southwest University of Science and Technology,Key Laboratory of Solid Waste Treatment and Resource Recycle, Southwest University of Science and Technology, Ministry of Education; Institute of Mineral Materials & Application, Southwest University of Science and Technology,Key Laboratory of Solid Waste Treatment and Resource Recycle, Southwest University of Science and Technology, Ministry of Education; Institute of Mineral Materials & Application, Southwest University of Science and Technology,Key Laboratory of Solid Waste Treatment and Resource Recycle, Southwest University of Science and Technology, Ministry of Education; Institute of Mineral Materials & Application, Southwest University of Science and Technology
Abstract:
Keywords:rich-titanium product  dilute sulfuric acid  leaching  separation  titanium component  recovery
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