Acyclic diene metathesis polymerization: History,methods and applications |
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Affiliation: | 1. Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany;2. Universidad Icesi, Facultad de Ciencias Naturales, Departamento de Ciencias Químicas, Calle 18 No. 122-135, Cali, Colombia;3. Arnold and Mabel Beckman Laboratories for Chemical Synthesis, California Institute of Technology, Pasadena, CA 91125, United States;4. The George and Josephine Butler Polymer Research Laboratory, Department of Chemistry and Center for Macromolecular Science and Engineering, University of Florida, Gainesville, FL 32611-7200, United States;1. Department of Polymer Science and Engineering, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China;2. Key Laboratory of Specialty Polymers, Grubbs Institute, Ningbo University, Ningbo 315211, China;1. AgroParisTech, Chaire Agro-Biotechnologies Industrielles (ABI), F-51100 Reims, France;2. AgroParisTech, UMR 1318 IJPB, F-78026 Versailles, France;3. INRA, UMR 1318 IJPB, F-78026 Versailles, France;4. AgroParisTech, UMR 782 GMPA, F-78850 Thiverval-Grignon, France;5. INRA, UMR 782 GMPA, F-78850 Thiverval-Grignon, France |
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Abstract: | Acyclic Diene Metathesis (ADMET) polymerization was established decades ago and has since developed into a robust and reliable technique. A wide range of different, new materials exhibiting unique properties has been produced via ADMET polymerization since its development. This versatile technique allows, through the right combination of monomer design and choice of catalyst, the synthesis of various functional polymers in addition to a precise control over primary structure. Systematic studies on precise ADMET polymers have greatly contributed to a better understanding of how branch identity and its distribution along the polymer backbone affect the thermal/electronic properties, crystallization, molecular dynamics and morphology of different materials. This article presents an extensive review of how ADMET started, the mechanism that underlies the structural features of ADMET polymers and the different strategies and techniques that have been developed over the years to overcome common synthetic challenges. Monomer synthesis methods are also discussed in detail, providing an important overview of the limitations and advantages of using ADMET as a polymerization technique. Many examples are given of functional ADMET polymers that have been developed by research groups all over the world. |
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Keywords: | Acyclic diene metathesis Step-growth polymerization Olefin metathesis Precision polymers Functional polymers |
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