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Conducting polymer-noble metal nanoparticle hybrids: Synthesis mechanism application
Affiliation:1. School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002 Jiangsu, PR China;2. Testing Center, Yangzhou University, Yangzhou 225009 Jiangsu, PR China;1. Laboratoire de Chimie Physique, UMR 8000-CNRS, Bât. 349, Université Paris-Sud, 91405 Orsay Cedex, France;2. Institut de Biologie Environnementale et Biotechnologie, UMR 7265-CNRS, CEA Marcoule, SBTN-Bât. 170-BP17171, 30207 Bagnols-sur-Cèze, France;1. School of Chemical Sciences, University of Auckland, New Zealand;2. MacDiarmid Institute for Advanced Materials and Nanotechnology, New Zealand;3. Department of Chemical and Materials Engineering, University of Auckland, New Zealand;1. Department of Chemistry & Biochemistry, Stephenson Life Sciences Research Center, University of Oklahoma, 101 Stephenson Parkway, Norman, OK, 73019, USA;2. Institute of Applied Bioresource Research, College of Animal Science, Zhejiang University, Yuhangtang Road 866, Hangzhou, Zhejiang, 310058, China;3. School of Materials Science and Engineering, Zhejiang University, Hangzhou, Zhejiang, 310027, China
Abstract:Recent research has established growing research interest in subject of conducting polymer (CP)-based hybrids due to their novel properties and potential applications in diverse fields. The incorporation of CPs with other materials can produce new hybrids showing distinct properties that are not observed in the individual components. Among numerous CP-based hybrids, CP and noble metal nanoparticle (NMNP) hybrids have attracted the most intensive attention in the past few years. The numerous functional groups and tunable chemical structures through redox in the main chains of CPs, make them as ideal supporters for NMNPs. The compact interactions and synergistic effects between CPs and NMNPs contribute to the increased performances in diverse applications. The purpose of this review focuses on state-of-the-art synthetic strategies, mechanisms and applications involved in CP-NMNP hybrids. Herein, CPs used are polyaniline (PANI), polypyrrole (PPY), polythiophene (PTH) and their derivatives; while NMNPs mainly refer to Au, Ag, Pt and Pd nanoparticles. Specifically, the topics include: 1) strategies and mechanisms involved in the synthesis of CP-NMNP hybrids; 2) potential applications of CP-NMNP hybrids in fields of catalysis, sensor, surface-enhanced Raman scattering (SERS), device and others. Finally, prospects and challenges for making advanced CP-NMNP hybrids are discussed.
Keywords:Conducting polymer  Polyaniline  Noble metal nanoparticle  Au  Hybrid  Catalysis  Sensor
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