Methodology for zinc phosphate pigment incorporation into polypyrrole matrix |
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Authors: | Denise?M?Lenz Michel?Delamar Email author" target="_blank">Carlos?A?FerreiraEmail author |
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Affiliation: | 1.LAPOL- PPGEM – Universidade Federal do Rio Grande do Sul,Porto Alegre,Brazil;2.ITODYS- Université Paris 7 – Denis Diderot,Paris,France |
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Abstract: | In this work, the incorporation of a commercial zinc phosphate pigment into polypyrrole (PPy) matrix during its electrochemical
synthesis on mild steel was studied in order to produce PPy/zinc phosphate composite films as a protective layer against corrosion.
Potassium nitrate, oxalic acid, tosylic acid and sodium salicylate solutions were used as electrolytes in cyclic voltammetry
and galvanostatic polarisation studies. The influence of synthesis parameters such as nature, concentration, pH and stirring
of the electrolyte on the degree of incorporation of the pigment was investigated, as well as time and current densities of
the electropolymerisation process. Their influence on current efficiency was also evaluated. Sodium salicylate was the only
electrolyte to show a high current efficiency in the polymerisation reaction and to yield a composite film with a reasonable
amount of zinc phosphate. In this electrolyte medium, X-ray photoelectron spectroscopy (XPS) analysis showed that zinc phosphate
may be found in the polymeric matrix: (i) as a conductive ionic minority form and (ii) as a non-conductive non-ionic majority
one for higher incorporation levels. Scanning electron microscopy (SEM) showed that zinc phosphate is heterogeneously distributed
on the surface of the polymer. |
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Keywords: | composite films mild steel polypyrrole zinc phosphate |
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