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Polymer aging insights available from modulus profiling data
Authors:Kenneth T Gillen  Roger L Clough
Abstract:A recently developed analytical technique, modulus profiling, conveniently allows the mechanical properties of elastomers to be mapped with spatial resclutions approaching 0.05 mm. Thus, spatial heterogeneities in modulus caused by processing and aging phenomena can be easily monitored. This paper describes some typical results from polymer aging studies, which Indicate the insights available from this technique. These include application of modulus profiling to understanding (1) mechanical property deterioration of Viton in an elevated temperature, gamma-radiation environment, (2) recent continuous stress-relaxation results, and (3) the role of ozone for non mechanically-stressed materials in high energy radiation environments.
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