Surfactants and self-assembly in carbon dioxide |
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| Affiliation: | 1. Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599, USA;2. Department of Chemical Engineering, North Carolina State University, Raleigh, NC 27695, USA;1. Department of Applied Chemistry, University of Johannesburg, P.O. Box 17011, Doornfontein Campus, 2028 Johannesburg, South Africa;2. Council for Scientific and Industrial Research, Meraka Institute, Centre for High Performance Computing, 15 Lower Hope Road, Rosebank, Cape Town 7700, South Africa;1. Department of Chemistry, Carleton University, Ottawa, ON K1S5B6, Canada;2. 3M Fuel Cell Components Group, 3M Center, St Paul, MN 55144, USA;3. SESAME, Allan 19252, Jordan;4. Humboldt-Universität zu Berlin, Experimentelle Biophysik, 10115 Berlin, Germany;5. Helmholtz-Zentrum Berlin, BESSY II, 12489 Berlin, Germany;1. Department of Materials Science, Fudan University, Shanghai 200433, China;2. School of Microelectronics, Fudan University, Shanghai 200433, China;3. Institute of Acoustics, School of Physics Science and Engineering, Tongji University, Shanghai 200092, China |
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| Abstract: | Amphiphilic compounds have played a vital role in the emergence of carbon dioxide in both its liquid and supercritical states as a versatile, environmentally benign solvent. This review serves to describe recent efforts in three major areas of the field: (1) polymeric amphiphile self-assembly in carbon dioxide solutions, (2) use of surfactants as stabilizing agents for polymerizations, and (3) studies involving ‘small molecule’ surfactant assemblies in carbon dioxide. |
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