Rapid solidification of Y3Al5O12 garnet from hypercooled melt |
| |
| Affiliation: | 1. The Institute of Space and Astronautical Science, 3-3-1 Yoshinodai, Sagamihara, Kanagawa 229-8510, Japan;2. Department of Materials Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan;1. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China;2. University of Chinese Academy of Sciences, Beijing 100049, China |
| |
| Abstract: | Containerless solidification of Y3Al5O12 garnet (YAG) was carried out using an aero-acoustic levitator to elucidate the solidification process beyond the hypercooling limit (ΔThyp). A YAG melt was seeded at different undercoolings by a SiO2 trigger needle. The apparent plateau after recalescence disappeared at around ΔT=500 K and the post-recalescence temperature (Tpost) decreased from the melting point with further increase in undercooling. ΔThyp of YAG was estimated to be 769 K using the specific heat of liquid that was evaluated by a heat-transfer calculation from the obtained cooling curves. Tpost decreased before reaching the estimated ΔThyp. Although this behavior was ascribed to heat extraction by the levitation gas, which suggests that the YAG melt did not solidify adiabatically due to the low thermal conductivity, the maximum undercooling of 1060 K indicates that the YAG melt solidified beyond ΔThyp. Moreover, the cellular morphology of YAG was observed even beyond ΔThyp. It can be seen that the cellular morphology is retained since the thermal supersaturation does not reach unity at ΔThyp due to the large kinetic effect. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
