Highly Active Catalyst from [PdCl2(NH2(CH2)12CH3)2] on NH4ZSM-5 |
| |
| Authors: | JA Díaz-Auñón J García-Martínez MC Román-Martínez C Salinas-Martínez de Lecea |
| |
| Affiliation: | (1) Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Alicante, Apdo. de Correos 99, 03080 Alicante, Spain |
| |
| Abstract: | A palladium catalyst highly active for the cyclohexene hydrogenation has been obtained by heterogenisation of PdCl2(NH2(CH2)12CH3)2] on zeolite NH4ZSM-5. TOF is more than twenty times higher than for the homogeneous catalyst or the activated carbon heterogenised complex. Changes in the electronic state of palladium have been observed by XPS analysis. Palladium reduction is produced upon heterogenisation on the NH4ZSM-5 zeolite. |
| |
| Keywords: | palladium– amine complex heterogenisation zeolite hydrogenation |
| 本文献已被 SpringerLink 等数据库收录！ |
