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聚苯胺防腐蚀涂料的研制及其性能
引用本文:高焕方,张胜涛,刘建平,刘超,彭超.聚苯胺防腐蚀涂料的研制及其性能[J].材料保护,2009,42(2).
作者姓名:高焕方  张胜涛  刘建平  刘超  彭超
作者单位:1. 重庆大学材料科学与工程学院,重庆,400030;重庆工学院化学与生物工程学院,重庆,400050
2. 化学与化工学院,重庆,400030
3. 重庆工学院化学与生物工程学院,重庆,400050
基金项目:重庆市教委科学技术研究项目 
摘    要:聚苯胺涂料具有优异的防腐蚀性能,目前,对它的开发已成为高分子导电材料应用和研究的新热点.为此,制备了本征态聚苯胺质量分数为0,1.5%,3.0%,5.0%,7.0%,10.0%的聚苯胺/环氧防腐蚀涂层,通过Tafel极化曲线及盐雾试验对比了其防腐蚀性能,并运用环境扫描电镜(SEM)观察了涂层的表面微观形貌.结果表明:聚苯胺含量对涂层的防腐蚀性能有较大影响,当涂层中聚苯胺含量较低时,随着聚苯胺在涂层中质量分数的增加,涂层的防腐蚀性能相应提高;随涂层中聚苯胺质量分数的进一步增大,涂层的防腐蚀效果开始下降;涂层中聚苯胺含量为5.0%时具有最佳的防腐蚀性能.

关 键 词:聚苯胺涂料  环氧  防腐蚀性能  微观形貌

Preparation of Polyaniline Anticorrosive Coating and Its Properties
GAO Huan-fang,ZHANG Sheng-tao,LIU Jian-ping,LIU Chao,PENG Chao.Preparation of Polyaniline Anticorrosive Coating and Its Properties[J].Journal of Materials Protection,2009,42(2).
Authors:GAO Huan-fang  ZHANG Sheng-tao  LIU Jian-ping  LIU Chao  PENG Chao
Affiliation:GAO Huan-fang1a,2,ZHANG Sheng-tao1b,LIU Jian-ping1,LIU Chao1,PENG Chan2(1a.School of Material Science , Engi-neering,Chongqing University,lb.Chemistry , Chemical En-gineering,Chongqing 400030,China,2.School of Chemistry , Biological Engineering,Chongqing Institute of Technology,Chongqing 400050,China)
Abstract:Polyaniline/epoxy resin anticorrosive coatings contai-ning 0,1.5%,3.0%,5.0%,7.0%,and 10.0% of eigenstate polyaniline were prepared.The anticorrosive performance of the coatings was compared by measuring Tafel curves and canying out salt-spray test,and the morphologies and microstructures of the coatings were analyzed using a scanning electron microscope.Re-sults indicated that the content of polyaniline had significant influ-ence on the anticorrosive performance of the coatings.Namely,the anticorrosive perf...
Keywords:polyaniline paint  epoxy resin  anticorrosive performance  micromorphology  
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