Nanoflakes to nanorods and nanospheres transition of selenious acid doped polyaniline |
| |
Authors: | Chellachamy Anbalagan Amarnath Jinwoo Kim Kyungbae Kim Jaeyoung Choi |
| |
Affiliation: | a Polymer Physical Chemistry Laboratory, Department of Chemistry, Hanyang University, 17 Haengdangdong, Sungdongku, Seoul 133-791, Republic of Korea b Pohang Accelerator Laboratory, San 31, Hyoja-dong, Nam-gu, Pohang 790-784, Republic of Korea |
| |
Abstract: | Morphology transition of selenious acid doped polyaniline from nanoflakes to nanorods and nanospheres was explored by changing the selenious acid-aniline (dopant-monomer) mole ratio in the aniline polymerization. The transition of polyaniline nanospheres to nanorods occurred when the dopant-monomer mole ratio was between 1 and 0.5. The formation of polyaniline nanorods was dominant when the dopant-monomer mole ratio is 0.5. At mole ratio 0.5, nanorods were obtained with the diameter at around 150 nm. At mole ratio 1, both the nanorods and nanospheres were formed and formation of the nanosphere is favored when the mole ratio is more than 1. When the mole ratio was low (0.125-0.03), polyaniline showed flakes like morphology. The morphology transition was studied by scanning electron microscopy and the molecular structure was confirmed by X-ray diffraction, FTIR and UV-vis spectroscopy. A simple and practical route to synthesize polyaniline nanostructures was demonstrated using selenious acid as effective dopant. The mechanism governing the formation of the polyaniline nanostructures is discussed. |
| |
Keywords: | Polyaniline Selenious acid Nanostructures |
本文献已被 ScienceDirect 等数据库收录! |
|