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Electrospinning jets and polymer nanofibers
Authors:Darrell H Reneker [Author Vitae]  Alexander L Yarin [Author Vitae]
Affiliation:a Department of Polymer Science, The University of Akron, Akron, OH 44325-3909, United States
b Department of Mechanical and Industrial Engineering, University of Illinois at Chicago, Chicago, IL 60607-7022, United States
Abstract:In electrospinning, polymer nanofibers are formed by the creation and elongation of an electrified fluid jet. The path of the jet is from a fluid surface that is often, but not necessarily constrained by an orifice, through a straight segment of a tapering cone, then through a series of successively smaller electrically driven bending coils, with each bending coil having turns of increasing radius, and finally solidifying into a continuous thin fiber. Control of the process produces fibers with nanometer scale diameters, along with various cross-sectional shapes, beads, branches and buckling coils or zigzags. Additions to the fluid being spun, such as chemical reagents, other polymers, dispersed particles, proteins, and viable cells, resulted in the inclusion of the added material along the nanofibers. Post-treatments of nanofibers, by conglutination, by vapor coating, by chemical treatment of the surfaces, and by thermal processing, broaden the usefulness of nanofibers.
Keywords:Drop  Droplet shape  Jet  Taylor cone  Envelope cone  Beads  Buckling  Interference colors  Doppler velocimeter  Meniscus  Straight segment  Tapered segment  Electrical bending instability  Instabilities of jets  Branching  Solidification  Collection  Conglutination  Ribbons  Glints  Encapsulation  Hierarchical structures  Spider silk  Silk nanofibers  Carbon nanofibers  Ceramic  Metal  Coated nanofibers  Polymer solutions  Polymer melts  Molten polymers  Polymer fluids  Non-Newtonian fluids  Viscosity  Charge transport  Electrodes  Fuel cells  Carbon nanotubes  Protein preservation  Metal nanofibers  Structures in interplanetary space  Exfoliated clay  Thermophotovoltaic device
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