Correlation of H2S solubility in aqueous MDEA solutions using electrolyte-modified Peng-Robinson plus association equation of state |
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| Authors: | Alireza Afsharpour Atefeh Afsharpour Mohammad Mohammadi-Khanaposhtani |
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| Affiliation: | 1. Young Researchers and Elite Club, South Tehran Branch, Islamic Azad University, Tehran, Iran;2. Faculty of Caspian, College of Engineering, University of Tehran, Rasht, Iran;3. Faculty of Fouman, College of Engineering, University of Tehran, Fouman, Iran |
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| Abstract: | In this survey, we use the emPR-CPA equation of state to model a ternary system of H2S solubility in MDEA aqueous solution at different solution compositions, temperatures, pressures, and acid gas loadings. For electrolyte part of the model, MSA theory and the Born term were used. There were 302 experimental data used in this work. To model a ternary system, at first pure components, then binary subsystems, and finally ternary system were modeled using a reactive bubble point pressure calculation method. An overall absolute average deviation percentage equal to 20.85 was achieved so that show the model efficiency for correlation of such systems. |
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| Keywords: | Cubic Plus Association emPR-CPA electrolyte model H2S solubility MDEA solution |
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