Biocatalytic synthesis of (S)-2-tridecanyl acetate and (S)-2-pentadecanyl acetate,aggregation pheromone components ofDrosophila mulleri andD. busckii,by enantioselective hydrolysis with lipase |
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| Authors: | Makoto Kamezawa Hojun Tachibana Takehiko Ohtani Yoshinobu Naoshima |
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| Affiliation: | (1) Konan Chemical Industry Co. Ltd., 5-21 Nakagawa-cho, 569 Takatsuki, Osaka, Japan;(2) Department of Biochemistry, Faculty of Science, Okayama University of Science, 1-1 Ridai-cho, 700 Okayama, Japan |
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| Abstract: | The two chiral pheromone acetates, (S)-2-tridecanyl acetate and (S)-2-pentadecanyl acetate, were synthesized with an enantiomeric excess (e.e.) of almost 100% byPseudomonas cepacia lipase-catalyzed hydrolysis of their corresponding racemic acetates in an acetone-water solvent system. |
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| Keywords: | Drosophila mulleri D busckii Diptera Drosophilidae aggregation pheromone (S)-2-tridecanyl acetate (S)-2-pentadecanyl acetate lipase hydrolysis enantioselectivity chirality |
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