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The structural and kinetic characteristics of Mg1.9Al0.1Ni alloy synthesized by mechanical alloying |
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| Authors: | Qian Li Kuo-Chih Chou Kuang-Di Xu Qin Lin Li-Jun Jiang Feng Zhan |
| Affiliation: | aSchool of Materials Science and Engineering Shanghai University, No. 275 mailbox, 149 Yanchang Road, Shanghai 200072, PR China bDepartment of Physical Chemistry, University of Science and Technology Beijing, Beijing 100083, PR China cResearch Center of Energy Materials and Technology, General Research Institute for Nonferrous Metals, Beijing 100088, PR China |
| Abstract: | The structural and kinetic characteristics of the mechanically alloyed Mg1.9Al0.1Ni were investigated. It was found that Mg1.9Al0.1Ni can absorb/desorb about 3.55/3.44 mass% H at a high rate and it has a hexagonal crystal structure as Mg2Ni. The hydriding/dehydriding (H/D) rates in the two-phase ( –β) region of Mg1.9Al0.1Ni were measured and studied at temperatures ranging from 553 to 623 K under an approximately isobaric condition. The obtained data of H/D rates indicated that hydrogen diffusion was the rate-controlling step through the hydride phase. A new model was successfully used to calculate the kinetic experimental results. It can be seen that theoretical calculation agrees well with experimental data. The corresponding activation energies are 47 600 and 54 500 J/mol H2 for H/D processes, respectively. |
| Keywords: | A Intermetallics miscellaneous B Hydrogen storage C Mechanical alloying and milling D Microstructure |
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