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Abnormal Grain Growth of Pb(Mg1/3Nb2/3)O3-35 mol% PbTiO3 Ceramics Induced by the Penetration Twin
Authors:Ui-Jin Chung  Jong-Keuk Park  Nong-Moon Hwang  Ho-Yong Lee  Doh-Yeon Kim
Affiliation:School of Materials Science and Engineering, and Center for Microstructure Science of Materials, Seoul National University, Seoul 151–744, Korea;Korea Research Institute of Standards and Science, Taejon 305–606, Korea;Division of Metallurgical and Materials Engineering, Sunmoon University, Asan 336–840, Korea
Abstract:Pb(Mg1/3Nb2/3)O3-35 mol% PbTiO3 (PMN-35PT) specimens with a 5 mol% excess PbO were prepared by excessive heat treatment at 1150°C to induce abnormal grain growth. Through electron backscatter diffraction analysis and the observation of a three-dimensional morphology, the abnormally grown PMN-35PT grains were found to be twinned crystals with penetration characteristics. The morphology of the PMN-35PT twinned crystal was crystallographically analyzed. The abnormal grain growth of PMN-35PT is suggested to be due to preferential growth at the reentrant angles formed by twins.
Keywords:grain growth    lead magnesium niobates    lead titanate
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