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激光熔覆生物陶瓷涂层及界面的热力学计算
引用本文:戴采云,张亚平,高加诚,王勇. 激光熔覆生物陶瓷涂层及界面的热力学计算[J]. 沈阳化工学院学报, 2006, 20(4): 264-267
作者姓名:戴采云  张亚平  高加诚  王勇
作者单位:1. 沈阳化工学院材料科学与工程学院,辽宁,沈阳,110142
2. 重庆大学材料科学与工程学院,四川,重庆,400044
摘    要:在医用金属材料表面形成一层生物陶瓷是制备高性能、高可靠性生物植入材料的有效途径.采用激光处理技术在钛合金表面同步合成及熔覆了以羟基磷灰石为主的生物陶瓷涂层复合材料,激光熔覆制备生物陶瓷涂层覆界面反应是非常复杂的过程,其中包括很多的化学反应,从物理化学角度对涂层覆界面反应进行热力学计算,计算结果表明:在该实验条件下,完全具备合成羟基磷灰石、磷酸钙等生物陶瓷涂层的热力学条件,而且也满足界面处发生化学反应生成钛酸钙等新相的条件。

关 键 词:激光熔覆  生物陶瓷涂层  界面  热力学计算
文章编号:1004-4639(2006)04-0264-04
收稿时间:2006-05-30
修稿时间:2006-05-30

Thermodynamic Calculation of Cladding Bio-ceramic Coating and Interface with Laser Beam
DAI Cai-yun,ZHANG Ya-ping,GAO Jia-cheng,WANG Yong. Thermodynamic Calculation of Cladding Bio-ceramic Coating and Interface with Laser Beam[J]. Journal of Shenyang Institute of Chemical Technolgy, 2006, 20(4): 264-267
Authors:DAI Cai-yun  ZHANG Ya-ping  GAO Jia-cheng  WANG Yong
Affiliation:1. Shenyang Insititute of Chemical Technology, Shenyang 110142, China; 2. Chongqing University, Chongqing 400044, China
Abstract:It is an effective method to create well-performing and highly dependable biomaterial that coats a bed of bio-ceramic on metals. Bio-ceramic coating composite material was composed on titanium alloy with laser scanning. The process of cladding coating and interface with laser beam was a complicated one due to many chemical reactions existing in this process. The free energy of many reactions on coating and interface is calculated. The results show that the free energy is negative under the condition of laser heating. So there are many new substances being made on coating and interface.
Keywords:laser cladding   bio-ceramic coating   interface   thermodynamic calculation
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