Synthesis, structure refinement at 296 K and physico-chemical characterizations of KMnHP3O10 |
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Authors: | J Mechergui |
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Affiliation: | Chemistry Department, Bizerta Science Faculty, 7021 Jarzouna, Bizerta, Tunisia |
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Abstract: | Potassium manganese(III) monohydrogentriphosphate KMnHP3O10 was synthesized by flux method and characterized by single-crystal X-ray diffraction, crystallizes in the monoclinic system with centric space group C2/c. The parameters of the unit cell are a = 12.104(1), b = 8.287(1). c = 9.150(1) Å, β = 110.97(1)° and Z = 4. The structure was solved at 296 K using 893 independent reflections and refined until R(F) = 0.022; wR(F2) = 0.045. The atomic arrangement of the title compound consists of MnO6 octahedra linked by hydrogentriphosphate anions to form a three-dimensional framework containing tunnels parallel to the c-axis where the K+ cations are inserted. The structure of KMnHP3O10 contains a single Mn site which is surrounded by typical Jahn-Teller 2 + 2 + 2] distorted octahedron. The title material has been also characterized by different physico-chemical techniques: powder X-ray diffraction, IR, NMR and CI spectroscopies and DTA-TGA-DSC thermal analysis. |
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Keywords: | C Impedance spectroscopy C Infrared spectroscopy C Nuclear magnetic resonance (NMR) C X-ray diffraction D Crystal structure |
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