| 带氨基磁性微球的制备及其对活性艳兰KN-R吸附行为 |
| |
| 引用本文： | 刘宏波,陈渊,郑鹏鹏,张佳华,谢明明,隋松,王耀. 带氨基磁性微球的制备及其对活性艳兰KN-R吸附行为[J]. 化工新型材料, 2012, 40(1): 101-104 |
| |
| 作者姓名： | 刘宏波 陈渊 郑鹏鹏 张佳华 谢明明 隋松 王耀 |
| |
| 作者单位： | 上海工程技术大学化学化工学院,上海,201620 |
| |
| 基金项目： | 上海优青科研基金，上海工程技术大学大学生创新项目基金 |
| |
| 摘 要： | 用无皂乳液聚合及种子聚合方法制备了Fe3O4@P(MMA-DVB-GMA)复合微球,用乙二胺对微球开环后制备得到了表面带氨基的磁性微球,用透射电镜(TEM)、热失重分析(TGA)对其进行了表征,并考察了其对染料KN-R的吸附性能。结果表明,制备的磁性微球粒径在150nm左右,大小均一,具备明显的核壳结构,磁含量为8wt%,在磁场作用下能够快速分离出来。该吸附剂在150min内达到吸附平衡,能够有效去除染料KNR,在4～9范围内pH对吸附剂吸附容量影响较小。
|
| 关 键 词： | 无皂乳液聚合 种子聚合 磁性 核壳结构 KN-R |
Magnetic microspheres bearing amino groups: preparation and adsorption behaviors towards reactive blue KN-R |
| |
| Liu Hongbo , Chen Yuan , Zheng Pengpeng , Zhang Jiahua , Xie Mingming , Sui Song , Wang Yao. Magnetic microspheres bearing amino groups: preparation and adsorption behaviors towards reactive blue KN-R[J]. New Chemical Materials, 2012, 40(1): 101-104 |
| |
| Authors: | Liu Hongbo Chen Yuan Zheng Pengpeng Zhang Jiahua Xie Mingming Sui Song Wang Yao |
| |
| Affiliation: | Liu Hongbo Chen Yuan Zheng Pengpeng Zhang Jiahua Xie Mingming Sui Song Wang Yao(College of Chemistry and Chemical Engineering,Shanghai University of Engineering Science, Shanghai 201620) |
| |
| Abstract: | Fe3O4@ P(MMA-DVB-GMA) mcirospheres were prepared by soap-free emulsion and seeded polymerization methods,and then reacted with ethylenediamine to yield amino groups for microspheres.The microspheres were characterized by transmission electron microscopy(TEM) and thermogravimetric analysis(TGA).Moreover,the adsorption performance of the spheres towards KN-R was investigated.The results showed that the magnetic microspheres were narrow-dispersed with size around 150nm and hadobvious core-shell spheric structure with Fe3O4 in the core and P(MMA-DVB-GMA) in the shell;the weight percentages of Fe3O4 was 8%;the microshperes showed high efficiency for the removal of KN-R that could achieved equilibrium in 150min;more important the variety of pH had little influence on the adsorption capacity from 4 to 9. |
| |
| Keywords: | soap-free emulsion polymerization seeded polymerization magnetism core-shell structure KN-R |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
