| 苯乙烯在炭黑表面的阴离子接枝聚合研究 |
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| 引用本文： | 刘长生.苯乙烯在炭黑表面的阴离子接枝聚合研究[J].武汉化工学院学报,1996,18(1):5-8. |
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| 作者姓名： | 刘长生 |
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| 摘 要： | 利用正丁基锂（ｎ－ＢｕＬｉ）与炭黑（ＣＢ）表面含氧基团反应制得了表面含－ＯＬｉ基团的反应型炭黑，以该炭黑与聚氧乙烯－聚氧丙烯－聚苯乙烯（（ＰＥＯ－ＰＰＯ－ＰＳ）ｎ）多嵌段聚合物组成的阴离子引发体系作活性中心，研究了苯乙烯在炭黑表面的阴离子接枝聚合反应。ＦＴ－ＩＲ，ＴＥＭ和ＤＳＣ分析表明在接枝炭黑表面存在着苯乙烯的聚合物，接枝炭黑在甲苯中有良好的分散稳定性。
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| 关 键 词： | 炭黑 苯乙烯 阴离子聚合 接枝聚合 |
A Study on Anionic Graft Polymerization of Styrene onto Carbon Black Surface |
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| Liu Changsheng,Liu Anhua,Wu Biyao,Jiang Ziduo.A Study on Anionic Graft Polymerization of Styrene onto Carbon Black Surface[J].Journal of Wuhan Institute of Chemical Technology,1996,18(1):5-8. |
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| Authors: | Liu Changsheng Liu Anhua Wu Biyao Jiang Ziduo |
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| Affiliation: | Liu Changsheng;Liu Anhua;Wu Biyao;Jiang Ziduo |
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| Abstract: | Using a reaction between oxygen-containing groups on carbon black surface and nbutyllithium,a reactive carbon black,carried with-OLi groups,was prepared.The anionic graft polymerization of styrene onto carbon black surface in the presence of polyoxyethylenepolyoxypropylene-polystyrene multiblock copolymer was investigated.According to determination of FT-IR,TEM and DSC and dispersion stability test,it is suggested that there were graft polymers on modified carbon black particles,the dispersed solution of modified carbon black in toluene had exellent dispersion stability. |
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| Keywords: | Carbon black Styrene Anionic polymerization Graft polymerization |
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