Comparative studies of “all sol–gel” electrochromic devices with optically passive counter-electrode films, ormolyte Li ion-conductor and WO3 or Nb2O5 electrochromic films

Laminated electrochromic (EC) devices are becoming increasingly important for making “smart” windows and switchable displays. Mostly, polymeric Li⁺ ionic conductors in combination with vacuum deposited active electrochromic and counter-electrode films are used. In this paper we report on the development of all sol–gel EC devices, that is, those where all three internal layers are prepared via the sol–gel route, including the ionically conductive inorganic–organic hybrid (ormolyte). The electrochemical and optical properties of EC devices are presented and the cycling stability and reversibility of their optical modulation assessed. The results show that WO₃/ormolyte/SnO₂ : Mo, WO₃/ormolyte/SnO₂ : Sb, WO₃/ormolyte/SnO₂ : Sb : Mo, Nb₂O₅/ormolyte/SnO₂ : Sb : Mo and WO₃/ormolyte/LiCo-oxide exhibit a transmission modulation dependent on the thickness of the active electrochromic and counter-electrode films and the thickness of the ormolyte layer. Electrochemical and optical properties of individual films are described and correlated with the stability of the all sol–gel EC devices.