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A ferromagnetic linear trinuclear Ni(II)-Schiff base complex supported by phenoxo and cinnamato bridges |
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| Authors: | Pampa Mukherjee Michael GB Drew Vassilis Tangoulis Marta Estrader Carmen Diaz Ashutosh Ghosh |
| Affiliation: | aDepartment of Chemistry, University College of Science, University of Calcutta, 92, A.P.C. Road, Kolkata 700 009, India;bSchool of Chemistry, The University of Reading, P.O. Box 224, Whiteknights, Reading RG 66AD, UK;cDepartment of Chemistry, Aristotle University of Thessaloniki, Thessaloniki 54124, Greece;dDepartament de Química Inorgànica, Universitat de Barcelona, Marti i Franques 1-11, 08028 Barcelona, Spain |
| Abstract: | A new linear trinuclear nickel(II) complex, Ni3(salme)2(OCn)4] (Hsalme = 2-(3-methylamino-propylimino)-methyl]-phenol, OCn = cinnamate), showing weak ferromagnetic coupling (J = 1.8(1) cm−1) through phenoxo and a novel tridentate bridging mode (1κ2OO′:2κO′) of the cinnamate ligand has been synthesized and structurally characterized by X-ray crystallography. |
| Keywords: | Nickel(II) Schiff base Bridging cinnamate X-ray structure Magnetic properties |
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