| 一锅煮法合成联结基团含羟基的季铵盐Geminie表面活性剂 |
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| 引用本文： | 赵秋伶,蔡秀琴.一锅煮法合成联结基团含羟基的季铵盐Geminie表面活性剂[J].广州化工,2009,37(4):124-125. |
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| 作者姓名： | 赵秋伶 蔡秀琴 |
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| 作者单位： | 渭南师范学院,陕西渭南,714000 |
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| 基金项目： | 渭南师范学院专项科研基金 |
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| 摘 要： | 以长链烷基叔胺、环氧氯丙烷、浓盐酸一锅煮的方法合成了联结基团含羟基的季铵盐Gemini表面活性剂。较佳合成条件为：反应物最佳配比为n（叔胺）：n（浓盐酸）：n（环氧氯丙烷）=2．2：1．1：1．0，反应时先加长链叔胺和盐酸，使之充分反应后再加环氧氯丙烷，在乙醇中回流条件下反应16h，收率达93．5％。
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| 关 键 词： | 长链烷基叔胺 环氧氯丙烷 浓盐酸 一锅煮 正交实验 合成Gemini表面活性剂 |
One Pot Synthesis of Quaternary-Ammonium Gemini Surfactant with Spacer Chain Containing Hydroxyl |
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| ZHAO Qiu-ling,CAI Xiu-qin.One Pot Synthesis of Quaternary-Ammonium Gemini Surfactant with Spacer Chain Containing Hydroxyl[J].GuangZhou Chemical Industry and Technology,2009,37(4):124-125. |
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| Authors: | ZHAO Qiu-ling CAI Xiu-qin |
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| Affiliation: | Department of Chemistryand Chemical Engineering;Weinan Teachers College;Shaanxi Weinan 714000;China |
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| Abstract: | Quaternary-ammonium Gemini surfactant was synthesized by one pot synthesis with spacer chain containing hydroxyl with long-chain alkyl tertiary amine, epoxy chloropropane and concentrated hydrochloric acid. The optimal synthesis conditions were obtained as follows: the molar ratio of tertiary amine to concentrated hydrochloric acid to epoxy chloro-propane=2.2:1.1:1.0, epoxy chloropropane was added after long-chain tertiary amine and concentrated hydrochloric acid were mixed, reaetion time was 16h in reluxin... |
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| Keywords: | long-chain alkyl tertiary amine epoxy chloropropane concentrated hydrochloric acid one pot orthogonal test synthesis quaternary-ammonium Gemini surfactant |
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