| 马来酸酐紫外辐照接枝高密度聚乙烯的制备及表征 |
| |
| 引用本文： | 李振中,何伟,马雅琳,张文熊.马来酸酐紫外辐照接枝高密度聚乙烯的制备及表征[J].辐射研究与辐射工艺学报,2006,24(6):341-344. |
| |
| 作者姓名： | 李振中 何伟 马雅琳 张文熊 |
| |
| 作者单位： | 北京工业大学材料科学与工程学院,北京,100022;中北大学分校高分子材料研究所,太原,030008;北京工业大学材料科学与工程学院,北京,100022;中北大学高分子与生物工程研究所,太原,030051 |
| |
| 摘 要： | 采用紫外辐照技术制备了高密度聚乙烯-马来酸酐接枝物（HDPE—g—MAH），并用红外光谱对接枝物进行了表征。研究了紫外光辐照时间、单体及引发剂浓度、第二单体苯乙烯（St）等因素对接枝率及凝胶含量的影响。结果显示，辐照时间为30s时，接枝效果最佳。马来酸酐（Maleic anhydride，MAH）用量的增加使接枝率不断上升，而接枝效率则在MAH含量为5．2％时达到最大值，之后开始下降。光引发剂二苯甲酮（Benzophenone，BP）的用量对接枝率及凝胶含量有重要影响，其用量为0．5％时接枝效果较好；St的加入使接枝物的凝胶含量显著降低。
|
| 关 键 词： | 马来酸酐 紫外辐照 接枝 高密度聚乙烯 |
| 收稿时间： | 2006-07-24 |
| 修稿时间： | 2006-09-21 |
Preparation and characterization of maleic anhydride grafted high density polyethylene induced by UV irradiation |
| |
| LI Zhenzhong,HE Wei,MA Yalin,ZHANG Wenxiong.Preparation and characterization of maleic anhydride grafted high density polyethylene induced by UV irradiation[J].Journal of Radiation Research and Radiation Processing,2006,24(6):341-344. |
| |
| Authors: | LI Zhenzhong HE Wei MA Yalin ZHANG Wenxiong |
| |
| Affiliation: | 1.College of Materials Science and Engineering, Beijing University of Technology, Beijing 100022; 2.Institute of Polymeric Material, North University of China, Ying Xin Branch, Taiyuan 030008; 3Institute of Macromolecules and Bioengineering of North University of China, Taiyuan 030051 |
| |
| Abstract: | Maleic anhydride grafted high density polyethylene (HDPE-g-MAH) were prepared by UV-irradiation. Factors of the irradiation time, monomer content, initiator content, and styrene as a co-monomer on the grafting rate and gel content of HDPE-g-MAH were studied. The results show that the optimal duration of UV-irradiation is 30s. The grafting rate increases with MAH content, while the grafting efficiency increases up to 5.2% MAH, where it drops. The content of benzophenone (BP) affects greatly the grafting rate and gel content, and the optimal BP content is 0.5%. Adding styrene into the graft system reduces apparently the gel content of HDPE-g-MAH. |
| |
| Keywords: | Maleic anhydride UV Irradiation Grafting High density polyethylene |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
