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Synergetic effect of thermo-photocatalytic oxidation of benzene on Pt-TiOe/Ce-MnOx
Authors:REN Chengjtm  ZHOU Lina  DUAN Yinwu  CHEN Yaoqiang
Affiliation:Key Laboratory of Green Chemistry and Technology of the Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China
Abstract:Pt-TiO2/Ce-MnOx catalysts were obtained by depositing TiO2 and platinum, respectively, on the Ce-Mn oxides prepared by co-precipitation method. The phases of CeO2 and anatase TiO2 were observed in the catalysts from X-ray diffraction (XRD) patterns. X-ray photoelectron spectroscopy (XPS) revealed that lattice oxygen and surface active oxygen were found to be the major components of O1s. The experiment results showed that the kinetic constant of thermo-photocatalysis was 7.6 times of the kinetic constant of single photocatalysis, and was 2.29 times of the kinetic constant sum of photocatalytic and thermal catalytic reaction.
Keywords:thermo-photocatalysis  synergetic effect  benzene  Ce-Mn oxides  TiO2  Pt  rare earths
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