Supramolecular Coordination Polymers by Self-assembling of Bis-monodentate Ligands with HgI2 |
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| Authors: | Xiaokang Li Xiaolin Fan Qingdao Zeng |
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| Affiliation: | 1.Gannan Normal University, Ganzhou, 341000, JiangXi, People’s Republic of China;2.Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Beijing, 100080, People’s Republic of China |
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| Abstract: | Two supramolecular coordination polymers, [HgI2(L1)·0.5H2O]∞ (1) and [HgI2(L2)·0.4CH3OH]∞ (2), have been prepared by ligands L1 (L1 = bis[4-(4- pyridylmethyleneamino)phenyl] ether) and L2 (L2 = N,N′-bis(3-pyridylmethyl)-diphthalic diimide) with HgI2, respectively. 1 formed an interestingly infinite cross-linked double helical structure, whereas 2 formed the one-dimensional zigzag chains, which are parallel with each other. |
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| Keywords: | Hg(II) complex, coordination polymers, bis[4-(4-pyridylmethyleneamino)- phenyl] ether, N,N′ -bis(3-pyridylmethyl)-diphthalic diimide |
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